- The elements of this nitrogen group is collectively called PNICOGENS and their compounds are PNICONIDES.
- Nitrogen is the most aboundant gas in atmosphere.
- Phosphorus is most reactive elements in these group and its colour is yellow ,these form is more reactive form of phosphorus. Which always kept under the water.
- General electronic configuration :- ns2,np3.
- In these group the elements have np3 which is outermost orbit and have exactly halffilled so these elements have fairly stability and hence these are inert elements. Eg . N is behave a inert elements.
- States of the elements in group:- nitrogen- gas , phosphorus:- solid vapourise easily , arsenic , Sb, Bi :- solid .
- Atomic size is increases down the group .
- The I.E energy is more than the group 14 . Elements ,.
- I.E is decreases the down the group.
- E.N is decreases the down the group.
- This group have E.N is more than the group 14 because of the halffilled outermost orbit so they are more stable.
- Due to increases in size and decrease in EN so their metallic character is increases down the group.
- Note :- basic nature is inversely proportional to the bond angle.
- Phosphorus, arsenic , antimony does not exist in diatomic molecules form , due to formation of the pπ - pπ bond between them.
- The melting point of this group is decreases upto the arsenic and then increase upto bismuth.
- Boiling point is increases down the group upto the bismuth. Exception Bi <Sb.
- All shows allotropes but exception the bismuth does not show the allotropic nature.
- Nitrogen have two solid and one gas allotropes.
- Phosphorus have five allotropes eg yellow red violet etc.
- White phosphorus is extract from the rock phosphate ( Ca3(Po4) ,SiO2 , coke). When the it exposed with the air it turns into the yellow.
- Red phosphorus is obtained from the heating yellow phosphorus in presence of the inert gases.
- Arsenic has 3 allotropes grey yellow black they have chair form structure.
- Group 15 shows the +3 and +5 oxidation state down the group the +3 oxidation state stability increases.
- This group shows the catenation property .
- Black phosphorus is good conductor of the electricity.
- White phosphorus shows the phosphorence property but red phosphorus does not show these property.
- Hydrides of the group15 has pyramidal shape bond angle decreases and boiling point is decreases down the group .
- Order of the basisity of hydrides of group 15 NH3 > PH3 > AsH3 > SbH3 .
Biomolecules Polysaccharide are not sweet in taste. All monosaccharides are reducing sugar. Monosaccharides are starting from carbon number 3. Starch contain amylose and amylopectin amylose contain bonding between c1 -c4 and amylopectin has c1-c6 bonding in their structure. Monomers: a)Lactose : 1) beta -D galactose 2)beta - D glucose. ...
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